SYNTHESIS SYNTHESIS SYNTHESIS SYNTHESIS SYNTHESIS SYNTHESIS SYNTHESIS SYNTHESIS AND C AND C HARACTERIZATI ARACTERIZATI ARACTERIZATIARACTERIZATIARACTERIZATI ARACTERIZATIARACTERIZATION OF DIMETHACRYLATE OF DIMETHACRYLATE OF DIMETHACRYLATE OF DIMETHACRYLATE OF DIMETHACRYLATE OF DIMETHACRYLATE OF DIMETHACRYLATE OF DIMETHACRYLATE OF

Abstract

The dimethacrylate macromonomer named bis (2 The dimethacrylate macromonomer named bis (2The dimethacrylate macromonomer named bis (2 The dimethacrylate macromonomer named bis (2The dimethacrylate macromonomer named bis (2 The dimethacrylate macromonomer named bis (2 The dimethacrylate macromonomer named bis (2The dimethacrylate macromonomer named bis (2 The dimethacrylate macromonomer named bis (2 The dimethacrylate macromonomer named bis (2The dimethacrylate macromonomer named bis (2 The dimethacrylate macromonomer named bis (2 The dimethacrylate macromonomer named bis (2 The dimethacrylate macromonomer named bis (2The dimethacrylate macromonomer named bis (2The dimethacrylate macromonomer named bis (2 The dimethacrylate macromonomer named bis (2 The dimethacrylate macromonomer named bis (2 The dimethacrylate macromonomer named bis (2 -hydroxy hydroxy -3-(méthacryloyloxy) propyl) (méthacryloyloxy) propyl) (méthacryloyloxy) propyl) (méthacryloyloxy) propyl) (méthacryloyloxy) propyl) (méthacryloyloxy) propyl) fumarate (HMPF) fumarate (HMPF) fumarate (HMPF) fumarate (HMPF)fumarate (HMPF) fumarate (HMPF) fumarate (HMPF)fumarate (HMPF), was synthesized by ring opening reaction was synthesized by ring opening reaction was synthesized by ring opening reaction was synthesized by ring opening reaction was synthesized by ring opening reaction was synthesized by ring opening reaction was synthesized by ring opening reaction was synthesized by ring opening reaction was synthesized by ring opening reaction was synthesized by ring opening reaction was synthesized by ring opening reaction was synthesized by ring opening reaction was synthesized by ring opening reaction was synthesized by ring opening reaction was synthesized by ring opening reaction was synthesized by ring opening reaction of epoxide function of epoxide function of epoxide function of epoxide function of epoxide function of epoxide function of epoxide function of epoxide function of epoxide function of glycidyl of glycidyl of glycidyl methacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnitemethacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnitemethacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnitemethacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnitemethacrylate (GMA) with maleic anhydride MA) in presence of Maghnitemethacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnite methacrylate (GMA) with maleic anhydride MA) in presence of Maghnite-H+ as a ca s a cas a cas a cas a catalyst at talyst at talyst at talyst at talyst at room temperature and temperature and temperature and temperature andtemperature andtemperature andtemperature and at free solvent. The Maghniteat free solvent. The Maghnite at free solvent. The Maghnite at free solvent. The Maghniteat free solvent. The Maghniteat free solvent. The Maghniteat free solvent. The Maghnite at free solvent. The Maghnite at free solvent. The Maghniteat free solvent. The Maghnite at free solvent. The Maghnite at free solvent. The Maghnite-H+ is a proton exchanged is a proton exchanged is a proton exchanged is a proton exchanged is a proton exchanged is a proton exchanged is a proton exchanged is a proton exchanged is a proton exchanged is a proton exchanged is a proton exchanged montmorillonite clay montmorillonite clay montmorillonite clay montmorillonite clay montmorillonite claymontmorillonite clay it i it iit is an Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was Algerian clay activated by sulfuric acid 0,23M. The HMPF was characterized by FTcharacterized by FT characterized by FT characterized by FTcharacterized by FT characterized by FTcharacterized by FTcharacterized by FTcharacterized by FT characterized by FT characterized by FTcharacterized by FT-IR, IR, IR, 1H NMR and H NMR and H NMR and H NMR and 13 C NMR spectroscopic techniques. A kC NMR spectroscopic techniques. A kC NMR spectroscopic techniques. A k C NMR spectroscopic techniques. A kC NMR spectroscopic techniques. A kC NMR spectroscopic techniques. A k C NMR spectroscopic techniques. A kC NMR spectroscopic techniques. A kC NMR spectroscopic techniques. A k C NMR spectroscopic techniques. A k C NMR spectroscopic techniques. A k C NMR spectroscopic techniques. A kC NMR spectroscopic techniques. A k C NMR spectroscopic techniques. A kC NMR spectroscopic techniques. A kC NMR spectroscopic techniques. A kinetic study was study was study was study was study was carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a carried out to determine the amount of catalyst (5, 10, 20 and 30%) which will give a better yield of the synthesis reaction. T better yield of the synthesis reaction. T better yield of the synthesis reaction. Tbetter yield of the synthesis reaction. T better yield of the synthesis reaction. T better yield of the synthesis reaction. T better yield of the synthesis reaction. T better yield of the synthesis reaction. T better yield of the synthesis reaction. T better yield of the synthesis reaction. T better yield of the synthesis reaction. Tbetter yield of the synthesis reaction. T better yield of the synthesis reaction. Tbetter yield of the synthesis reaction. Tbetter yield of the synthesis reaction. T better yield of the synthesis reaction. T better yield of the synthesis reaction. Tbetter yield of the synthesis reaction. The yield of the reaction was 62. he yield of the reaction was 62.he yield of the reaction was 62. he yield of the reaction was 62. he yield of the reaction was 62. he yield of the reaction was 62. he yield of the reaction was 62.he yield of the reaction was 62.he yield of the reaction was 62. he yield of the reaction was 62. he yield of the reaction was 62. he yield of the reaction was 62. he yield of the reaction was 62. 23% for a quantity of 3% for a quantity of 3% for a quantity of 3% for a quantity of 3% for a quantity of 3% for a quantity of 3% for a quantity of