Browsing by Author "Khiari, S."
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Item Spectroscopic Proprieties Of Crystals Mf2 (m=cd, Sr, Ba) Doped To Rare Earth Ions(University of Eloued جامعة الوادي, 2012-01-01) Diaf, M.; Khiari, S.; Labbaci, K.; Guerbous, L.; Jouart, J. P.In the present work, we are interested by studying the spectroscopic properties for optical applications, mainly laser amplification, of MF2 crystals, where M is an alkaline earth (Ba, Sr) or Cadmium (Cd) doped with rare earth ions (Tb3+, Er3+, Ho3+). So far, we present the absorption and emission properties and also the fluorescence dynamics at room temperature of visible and near infrared transitions of the Er3+ ion doping these matrices. We also use the formalism of Judd-Ofelt by use of absorption spectra recorded at room temperature in order to identify the spectroscopic properties inherent in all radiative transitions which can occur.Item Spectroscopie des céramiques pour l’amélioration du rendement des cellules photovoltaïques(University of Eloued جامعة الوادي, 2018-02-05) Bensalem, C.; Boulma, E.; Diaf, M.; Khiari, S.This optical investigation of glass-ceramics formed by annealing glasses with compositions 50 GeO2 - 40 PbO - 10 PbF2 - x EuF3, x = [0.5; 1; 1.5; 2] and polycrystalline ceramics with composition 100 PbF2, y EuF3, with y = 5, 10, 15 and 20. For each material, the photoluminescence spectrum and the photoluminescence lifetimes of the 5D0, 5D1 and 5D2 Eu3+ levels are measured. Occurrence of β-PbF2: Eu3+ nanocrystallites in the glass-ceramics is confirmed and total ceramisation requires more than 10 % of EuF3 with respect to PbF2 in the starting glass. In the β-PbF2: Eu3+ ceramics and glass-ceramics, Eu3+ ions replace Pb2+ in their regular cubic site, but they interact together to form dimmers and higher nuclearity clusters. For the EuF3 rates investigated here, there are no isolated Eu3+ ions in the PbF2 lattice. A preliminary investigation of the optical properties of co-doped β-PbF2: Gd3+- Eu3+ ceramics was also performed. It shows that efficient Gd3+ → Eu3+ energy transfer occurs in these ceramics. The Pb2+ ions of the lattice may also be involved in the energy transfer process.