Hadjout, S.Haraoubia, R.Benabdelghani, Z.2020-11-022020-11-022017-01-01Article in Journal of Fundamental and Applied Sciences Vol 09, N 011112-9867http://dspace.univ-eloued.dz/handle/123456789/7362Article in Journal of Fundamental and Applied Sciences Vol 09, N 01The acyclic and cyclic monothio-orthoester monomers were synthesized by modification of aromatic monomers containing dithioester function in the side chain. Reversible addition-fragmentation chain transfer (RAFT) polymerization was employed for the preparation of polymers containing a dithioester end as macro-chain transfer agents (macro-CTA) using 4-benzyl methyldithiobenzoate (BMDTB) as chain transfer agent (CTA) and 2,2-azobisisobutyronitrile (AIBN) as initiator. A series of diblock copolymers were prepared by RAFT copolymerization of MVDTB, MMMS and MVPOCO, using the different macro-chain transfer agents (macro-CTA) and AIBN as initiator. All polymerizations were carried out at 60 °C for 24 or 30 hours in dry THF. Homopolymers and diblock copolymers are characterized by 1H NMR, 13C NMR, IR, SEC, DSC and TGA.enDithioesters, monothio-orthoesters, RAFT polymerization.Article